f-block Metal Chemistry
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Organometallic neptunium(III) complexes
Studies of transuranic organometallic complexes provide particularly valuable insight into covalent contributions to the metal-ligand bonding, in which the subtle differences between the transuranium actinide ions and their ... -
ThBisImido https://doi.org/10.1021/jacs.5b06630
Molecules containing actinide-nitrogen multiple bonds are of current interest as simple models for new actinide nitride nuclear fuels, and potential catalytic activation of inert hydrocarbon C-H bonds. Molecules with ... -
Characterizing pressure-induced uranium C-H agostic bonds
Under pressure: The diuranium(III) compound [UN''2]2(μ-η6:η6-C6H6) (N''=N(SiMe3)2) has been studied using variable, high-pressure single-crystal X-ray crystallography, and density functional quantum chemistry. In this ... -
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